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zeige Details Nikishin, G. I., Ogibin, Yu. N., ... Unusual direction of the radical reaction of esters with ethylenic compounds
in: Russian chemical bulletin , ISSN 1573-9171, Vol. 20 (5. 1971), p. 980-985
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1971
Conclusions 1. A study was made of the addition reaction, initiated by peroxides, of diethyl malonate, dimethyl succinate and ethyl monochloroacetate to the polyhaloolefins — to hexafluoropropylene, trichloroethylene and tetrachloroethylene. 2. The reaction proceeds by an anomalous direction: the α-carbon atom of the alcohol portion of the ester molecule takes part either exclusively or predominantly in the formation of the new carbon — carbon bond of the adducts. 3. The reaction of esters with trichloro- and tetrachloroethylene is accompanied by the elimination of hydrogen chloride and leads to the respective formation of either the 1-(dichlorovinyl) or 1-(trichlorovinyl) derivatives of alkyl esters of carboxylic acids.
Copyright: Copyright 1971 Consultants Bureau
beteiligte Personen: Nikishin, G. I. , Ogibin, Yu. N. , Lebedev, V. N.
Format: Elektronisch
Erschienen: 1971.
Serie: Springer Online Journal Archives 1860-2000 [Dig. Serial]
Schlagwörter:
URL: http://dx.doi.org/10.1007/BF00862208

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